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Oxidative Palladium (Ii)-catalyzed Carbocyclization: Control of Alkene Geometry or Relative Configuration Sandeep Reddy Kandukuri
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Oxidative Palladium (Ii)-catalyzed Carbocyclization: Control of Alkene Geometry or Relative Configuration
Sandeep Reddy Kandukuri
The present work is dedicated to the development and application of oxidative palladium(II)-catalyzed carbocyclizations. A general procedure for an aerobic palladium(II)-catalyzed endo cyclization of indole derivatives is presented. Further application of this new methodology in the synthesis of C-2 alkenylated indoles in diastereomerically pure form is also reported. The other methodologies involves hydroxy-directed diastereotopic group selection of prochiral bis(homoallylic) alcohols and enantioselective Fujiwara?Moritani cyclizations. In addition to this, the book also details on the indole directed aerobic dehydrogenation of cyclohexenes.
| Medios de comunicación | Libros Paperback Book (Libro con tapa blanda y lomo encolado) |
| Publicado | 14 de agosto de 2013 |
| ISBN13 | 9783848498802 |
| Editores | LAP LAMBERT Academic Publishing |
| Páginas | 280 |
| Dimensiones | 150 × 16 × 226 mm · 435 g |
| Lengua | Alemán |